Product ID:NAVAL DISTILLATE
MSDS Date:07/07/1998
FSC:9140
NIIN:00-273-2378
Status Code:A
MSDS Number: CLJTR

ARCO PRODUCTS CO DIV OF ATLANTIC RICHFIELD CO

333 S HOPE ST
LOS ANGELES, CA 90071-0570
US

Emergency Phone: 213-222-3212

Info Phone: 213-486-0773/800-322-2726 INFO

Cage: 9V333

ARCO PRODUCTS CO DIV OF ATLANTIC RICHFIELD CO

512570 LOS ANGELES, CA 90071-0570 US

Telephone: 213-486-0773/800-322-2726 INFO

Cage: 9V333

HYDROCARBONS W/BOILING PT OF 325F TO 698F

CAS: 68334-30-5

Fraction By Weight: 100%

NAPHTHALENE

CAS: 91-20-3

RTECS: OJ0525000

Fraction By Weight: 1-2%

OSHA PEL 15 MG/M3;10 PPM

ACGIH TLV: 15 MG/M3;10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

NAPHTHALENE, 1-METHYL-

CAS: 90-12-0

RTECS: QJ9630000

Fraction By Weight: 0.1-1%

NAPHTHALENE, 2-METHYL-

CAS: 91-57-6

RTECS: OJ9635000

Fraction By Weight: 0.1-1%

PHENANTHRENE

CAS: 85-01-8

RTECS: SF7175000

Fraction By Weight: 0.1-1%

OSHA PEL 0.2 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

OSHA PEL 100 PPM

ACGIH TLV: 525 MG/M3;100 PPM

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:LONG TERM TESTS PRODUCED KIDNEY DAMAGE
AND SKIN TUMORS ON LABORATORY ANIMALS.RESPIRATORY IRRITATION AND
REVERSIBLE PULMONARY EFFECTS ARE ASSOCIATED WITH EXPOSURE TO DIESEL
EXHAUST.INHALATION/INGESTION : AT CONCENTRATIONS > THAN THE
RECOMMENDED EXPOSURE LIMITS, CAN CAUSE IRRITATION OF NOSE, THROAT,
LUNGS, HEADACHE, DIZZINESS, LOSS OF COORDINATION, FATIGUE,
NAUSEA,GASTROINTESTINAL PROBLEMS AND LABORE D BREATHING. EYE: NOT
EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT EYE DAMAGE. SKIN:
MODERATE SKIN IRRITATION. EXPOSURE TO SUNLIGHT MAY INCREASE THE
DEGREE OF SKIN IRRITATION.
Effects of Overexposure:IRRITATION OF NOSE, THROAT, LUNGS, HEADACHE,
DIZZINESS, LOSS OF COORDINATION, FATIGUE, NAUSEA, LABORED
BREATHING.VOMITING,DIARRHEA AND RESTLESNESS.PROLONGED/REPEATED SKIN
EXPOSURE, INHALATION OR INGES TION OF THIS MATERIAL MAY RESULT IN
ADVERSE DERMAL OR SYSTEMIC EFFECT.
Medical Cond Aggravated by Exposure:SKIN: IRRITATION. INGESTION:
IRRITATION OF MOUTH, THROAT AND GASTROINTESTINAL TRACT, NAUSEA,
VOMITING, DAIRRHEA, RESTLESSNESS. HEADACHE, DIZZINESS, DROWSINESS,
LOSS OF COORDINATION, FATIGUE, NAUSEA

First Aid:INHALTION: IMMEDIATELY MOVE PERSONNEL TO AREA OF FRESH AIR.
FOR RESPIRATORY DISTRESS, GIVE OXYGEN, ADMINISTER CPR IF
NEEDED.OBTAIN MEDICAL ATTENTION. EYE: FLUSH EYES WITH CLEAN
LOW-PRESSURE WATER FOR AT LEAST 15 MINUTES. IF PAIN OR IRRITATION
PERSISTS AFTER FLUSHING, OBTAIN MEDICAL ATTENTION. SKIN: PROMPTLY
REMOVE CONTAMINATED CLOTHING. THOROUGHLY WASH AFFECTED SKIN WITH
SOAP AND WATER. IF THERE A RE SIGNS OR SYMPTOMS OF IRRITATION,
OBTAIN MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING SINCE
ASPIRATION INTO THE LUNGS MAY CAUSE CHEMICAL PNEUMONIA.OBTAIN
MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:=60.C, 140.F
Autoignition Temp:=257.2C, 495.F
Lower Limits:0.6
Upper Limits:7.5
Extinguishing Media:FOAM, DRY CHEMICAL, HALON, CARBON DIOXIDE, WATER
FOG, WATER AND WATER FOG MAY BE USED TO COOL THE FIRE BUT MAY NOT
EXTINGUISH THE FIRE.
Fire Fighting Procedures:FOR FIRES INVOLVING THIS MATERIAL, DO NOT
ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE
EQUIPMENT. THIS MAY INCLUDE SELF-CONTAINED BREATHING APPARATUS TO
PROTECT AGAINST HAZARDOU S EFFECTS OF COMBUSTION PRODUCTS AND
OXYGEN DEFICIENCIES. COOL TANKS AND CONTAINERS EXPOSED TO FIRE WITH
WATER.
Unusual Fire/Explosion Hazard:MODERATELY COMBUSTIBLE! WHEN HEATED ABOVE
THE FLASH POINT, THIS MATERIAL RELEASE FLAMMABLE VAPORS WHICH, IF
EXPOSED TO AN IGNITION SOURCE, CAN BURN IN THE OPEN OR BE EXPLOSIVE
IN CONFINED SPACES. MIST S OR SPRAYS MAY BE FLAMMABLE AT
TEMPERATURES BELOW THE NORMAL FLASH POINT.

Spill Release Procedures:CONTAIN SPILL,EVACUATE NON-ESSENTIAL
PERSONNEL,AND SAFELY STOP FLOW. ON HARD SURFACES,SPILLED MATERIAL
MAY CREATE A SLIPPING HAZARD.EQUIP CLEANUP CREWS WITH PROPER
PROTECTIVE EQUIPMENT AND ADVISE OF H AZARDS.CLEAN UP BY RECOVERING
AS MUCH SPILLED OR CONTAMINATED MATERIALS AS POSSIBLE AND PLACING
INTO CLOSED CONTAINERS.CONSULT WITH AN ENVIRONMENTAL PROFESSIONAL
FOR THE FEDERAL,STATE AND LOCALCLEANUP

Handling and Storage Precautions:SPECIAL SLOW LOAD PROCEDURES FOR
"SWITCH LOADING" MUST BE FOLLOWED TO AVOID THE STATIC IGNITION
HAZARD THAT CAN EXIST WHEN THIS MATERIAL IS LOADED INTO TANKS
PREVIOUSLY CONTAINING GASOLINE OR OTHER LO W FLASH POINT PRODUCTS.
KEEP CONTAINERS CLOSED AND AWAY FROM HEAT& IGNITION SOURCES!
Other Precautions:EMPTY COMTAINERS RETAIN SOME LIGUID AND VAPOR
RESIDUES, AND HAZARD PRECAUTIONS MUST BE OBSERVED WHEN HANDLING
EMPTY CONTAINERS.WARNING:USE OF ANY HYDROCARBON FUEL IN SPACES
WITHOUT ADEGUATE VENTILATIO N MAY RESULT IN GENERATION OF HAZARDOUS
LEVELS OF COMBUSTION PRODUCTS AND INADEGUATE OXYGEN LEVELS F OR
BREATHING.

Respiratory Protection:NIOSH/MSHA APPROVED AIR-PURIFYING RESPIRATOR
WITH AN ORGANIC VAPOR CARTRIDGE MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS MAY EXCEED THE EXPOSURE
LIMITS.THE PROTECTION PROVIDED BY AIR-PURIFYING RESPIRATORS IS
LIMITED. USE A POSITIVE PRESSURE AIR-SUPPLIED RESPIRATOR IF THERE
IS ANY POTENTIAL FOR AN UNCONTROLLED RELEASE.
Ventilation:USE ADEQUATE VENTILATION TO KEEP VAPOR & MIST
CONCENTRATIONS OF THIS MATERIAL BELOW THE OCCUPATIONAL EXPOSURE
LIMITS.ELECTRICAL EQUIPMENT SHOULD COMPLY WITH NEC
Protective Gloves:CLEAN IMPERVIOUS GLOVES
Eye Protection:CHEMICAL-TYPE GOGGLES OR FACE SHIELD
Other Protective Equipment:CLEAN IMPERVIOUS CLOTHING SUCH AS GLOVES,
APRON, BOOTS AND FACIAL PTOTECTION. NITRILE, NEOPRENE, VITRON
PROTECTIVE CLOTHING MATERIAL RECOMMENDED. IMPREVIOUS BOOTS&OIL
RESISTANT COATED TYVEK SUIT.
Work Hygienic Practices:USE GOOD PERSONNEL HYGIENE PRACTICES. IN CASE
OF SKIN CONTACT, WASH WITH MILD SOAP AND WATER OR WATERLESS HAND
CLEANER. WASH HANDS AND OTHER EXPOSED AREAS THOROUGHLY BEFORE
EATING, DRINKING, SMOKING.
Supplemental Safety and Health
SYMONYMS: DIESEL FUEL OIL, MARINE DIESEL (FORMER NAME) (MEETS MILITARY
SPECIFICATION MIL-F-16884G), PETROLEUM DISTILLATE FUEL, F76.

HCC:V6
Boiling Pt:B.P. Text:350-725F
Melt/Freeze Pt:=-9.4C, 15.F
Vapor Pres:0.04@100F(REID-PSIA)
Spec Gravity:AP 0.86
pH:N/AP
Viscosity:AP 3@100F (D-445)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT YELLOW TO AMBER-COLORED LIQUID; KEROSENE
ODOR.
Percent Volatiles by Volume:SLIGHT

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALIS, AND OXIDIZERS SUCH AS LIQUID CHLORINE AND
OXYGEN.
Stability Condition to Avoid:HEAT AND IGNITION SOURCES.
Hazardous Decomposition Products:BURNING OR EXCESSIVE HEATING MAY
PRODUCE CARBON MONOXIDE AND OTHER HARMFUL GASES OR VAPORS INCLUDING
OXIDES OF SULFUR AND NITROGEN.

Waste Disposal Methods:MAXIMIZE RECOVERY FOR REUSE OR RECYCLING.CONSULT
W/ENVIRONMENTAL PROFESSIONAL TO DETERMINE IF STATE OR FEDERAL
REGULATIONS WOULD CLASSIFY SPILLED OR CONTAMINATED MATERIALS AS A
HAZARDOUS WASTE.USE ONL Y APPROVED
TRANSPORTERS,RECYCLERS,TREATMENT,STORAGE OR DISPOSAL
FACILITIES.COMPLY WITH ALL FEDERAL,S TATE AND LOCAL LAWS PERTAINING
TO WASTE MANAGEMENT

Toxicological Information:TOXICITY STUDIES ON THIS MATERIAL RESULTED IN
LC50 VALUES GREATER THAN 4.8 MG/L INDICATING A LOWER LEVEL OF
TOXICITY.HOWEVER DURING EXPOSURE THE MATERIAL CAUSED LABORED
BREATHING, GASPING,EYES CLOSED, REDUCED ACTIVITY, HUNCHED
APPEARANCE,NASAL DISCHARGE INCOORDINATION AND TERMORS.EXPOSURE TO
DIESEL EXHAUST MAY RESULT IN REVERSIBLE SYMPTOMS,SUCH AS
RESPIRATORY TRACT IRRITATION (WHEEZING, CHEST TIGHT NESS), MUCOUS
MEMBRANE IRRITATION,CNS EFFECTS (HEADACHE AND
LIGHTHEADEDNESS),NAUSEA,VOMITING AND HEARTBURN.NO EYE CONTACT
IRRITATION HAS BEEN REPORTED. SKIN CONTACT STUDIES RESULTED IN
MODERATE SKIN I RRITATION.INGESTION:CAUGH,PNEUMONIA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT AVAILABLE PER MSDS

Transport Information:UN PROPER SHIPPING NAME: FUEL OIL NO.2. UN HAZARD
CLASS 3. UN NUMBER: NA 1993. UN PACKING GROUP: PGIII

SARA Title III Information:DELAYED (CHRONIC) HEALTH HAZARD, IMMEDIATE
(ACUTE) HEALTH HAZARD, FIRE HAZARD. SECTION 313, THIS PRODUCT
CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS ESTABLISHED BY SARA TITL E III, COMPONENT NAME:
NAPHTHALENE.
Federal Regulatory Information:TSCA: ALL COMPONENTS OF THIS PRODUCT ARE
LISTED ON THE TSCA INVENTORY. CERCLA: NO CHEMICALS IN THIS PRODUCT
ARE SUBJECT TO THE REPORTING REQUIREMENTS OF CERCLA. CALIFORNIA
SAFE DRINKING WATER ACT: CHE MICALS KNOWN TO THE STATE TO CAUSE
CANCER, BIRTH DEFECTC, OR OTHER REPRODUCTIVE HARM ARE FOUND IN
GASOLINE, CRUDE OIL, AND MANY PETROLEUM PRODUCTS AND THEIR VAPORS.
THIS PRODUCT MAY CONTAIN TRACE AMOU NT OF BENZENE, TOLUENE WHICH
ARE LISTED BY THE STATE OF CALIFORNIA TO CAUSE CANCER OR BIRTH
DEFECTS OR OTHER REPRODUCTIVE HARM.
State Regulatory Information:CALIFORNIA SAFE DRINKING WATER ACT:
CHEMICALS KNOWN TO THE STATE TO CAUSE CANCER, BIRTH DEFECTC, OR
OTHER REPRODUCTIVE HARM ARE FOUND IN GASOLINE, CRUDE OIL, AND MANY
PETROLEUM PRODUCTS AND THEIR VAPO RS. THIS PRODUCT MAY CONTAIN
TRACE AMOUNT OF BENZENE, TOLUENE WHICH ARE LISTED BY THE STATE OF
CALIFORNIA TO CAUSE CANCER OR BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM.